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Studies on the reactions of α,β-enones with allyl indium reagent; effects of TMSCI as promoter on regioselectivity
- Lee, Philho;
- Ahn, Hyosoon;
- Lee, Kooyeon;
- Sung, Sun-young;
- Kim, Sunggak
Citations
SCOPUS
85초록
Regioselectivity on the reactions of α,β-enones with allyl indium reagents in the presence of TMSCl was systematically studied. 2-Cyclohexen-1-one, (R)-carvone, 2-cyclohepten-1-one and chalcone produced 1,4-addition products in good yields, whereas 2-cyclopenten-1-one, 2-methylcyclopenten-1-one, 4,4-dimethylcyclohexen-1-one and acyclic α,β-enones afforded 1,2-addition products. © 2000 Elsevier Science Ltd.
키워드
Indium; Michael reaction; Promoter
- 제목
- Studies on the reactions of α,β-enones with allyl indium reagent; effects of TMSCI as promoter on regioselectivity
- 저자
- Lee, Philho; Ahn, Hyosoon; Lee, Kooyeon; Sung, Sun-young; Kim, Sunggak
- 발행일
- 2001
- 유형
- Article
- 권
- 42
- 호
- 1
- 페이지
- 37 ~ 39