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A new and general one-pot synthesis of propargyl alcohols from esters
- Chae, Min Jung;
- Jeon, Ah Ram;
- Livinghouse, Tom;
- An, Duk Keun
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12초록
Intermediates easily prepared by partial reduction of various esters with LDBBA as a reducing agent smoothly react with lithium acetylides to give propargyl alcohols, without isolation of partial reduction intermediates, in good yields (73-83%).
키워드
T-BUTOXYALUMINUM HYDRIDE; IN-SITU GENERATION; ENANTIOSELECTIVE SYNTHESIS; GAMMA-HYDROXY-ALPHA,BETA-ACETYLENIC ESTERS; ALPHA,BETA-UNSATURATED ESTERS; NUCLEOPHILIC-ADDITION; TERMINAL ACETYLENES; MILD CONDITIONS; ALDEHYDES; ALKYNYLATION
- 제목
- A new and general one-pot synthesis of propargyl alcohols from esters
- 저자
- Chae, Min Jung; Jeon, Ah Ram; Livinghouse, Tom; An, Duk Keun
- 발행일
- 2011
- 유형
- Article
- 권
- 47
- 호
- 11
- 페이지
- 3281 ~ 3283
- 언어
- ENG
- 출판사
- ROYAL SOC CHEMISTRY
- 발행국가
- 영국
- 분량
- 3 페이지
- ISSN
- E 1364-548X
P 1359-7345