Synthesis and spectroscopic behaviour of metal complexes of meso-alkylidenyl carbaporphyrinoids and their expanded analogues

Abebayehu, Abeje; Park, Dowoo; Hwang, Seonah; Dutta, Ranjan; Lee, Chang-Hee

doi:10.1039/c5dt04566e

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Synthesis and spectroscopic behaviour of metal complexes of meso-alkylidenyl carbaporphyrinoids and their expanded analogues

Abebayehu, Abeje;
Park, Dowoo;
Hwang, Seonah;
Dutta, Ranjan;
Lee, Chang-Hee

Citations

WEB OF SCIENCE

8

Citations

SCOPUS

10

초록

Treatment of meso-malonylidene-(m-benzi)porphyrin and meso-malonylidene-(m-benzi)pentaphyrin with Pd(II), Au(III), Ni(II) and Ag(I) afforded the corresponding metal complexes. The synthesized metal complexes were characterized by spectroscopy including single crystal X-ray, NMR and mass spectrometry. Most metal complexes were stable in solution. The metal complexes showed strong absorption in the near IR region.

키워드

DOUBLE-BONDS; PORPHYRINS; BENZIPORPHYRINS; CHEMISTRY; PYRROLE; AROMATICITY; ISOMER; FAMILY; RING; IRON

제목: Synthesis and spectroscopic behaviour of metal complexes of meso-alkylidenyl carbaporphyrinoids and their expanded analogues

저자: Abebayehu, Abeje; Park, Dowoo; Hwang, Seonah; Dutta, Ranjan; Lee, Chang-Hee

DOI: 10.1039/c5dt04566e

발행일: 2016

유형: Article

저널명: Dalton Transactions

권: 45

호: 7

페이지: 3093 ~ 3101