Synthesis of Indenes via Bronsted Acid Catalyzed Cyclization of Diaryl- and Alkyl Aryl-1,3-dienes

  • Eom, Dahan
  • Park, Sangjune
  • Park, Youngchul
  • Ryu, Taekyu
  • Lee, Phil Ho
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초록

Substituted indenes can be synthesized via the Bronsted acid catalyzed cyclization of diaryl- and alkyl aryl-1,3-dienes. In this approach, treatment of symmetric or unsymmetric diaryl- and alkyl aryl-1,3-dienes with a catalytic amount of trifluoromethanesulfonic acid gives a variety of indene derivatives in good to excellent yields under mild conditions.

키워드

REGIOSELECTIVE SYNTHESISCOUPLING REACTIONSCONVENIENT SYNTHESISASYMMETRIC-SYNTHESISINDANYL CATIONSDERIVATIVESCARBOCYCLIZATIONCARBOANNULATIONREARRANGEMENTKETONES
제목
Synthesis of Indenes via Bronsted Acid Catalyzed Cyclization of Diaryl- and Alkyl Aryl-1,3-dienes
저자
Eom, DahanPark, SangjunePark, YoungchulRyu, TaekyuLee, Phil Ho
DOI
10.1021/ol302271w
발행일
2012-11-02
유형
Article
저널명
Organic Letters
14
21
페이지
5392 ~ 5395