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초록
An efficient synthetic method of Z-selective 3-ethoxycarbonyl-2-halo-1,3-dienes and 3-vinyl-2-halo-1,3-dienes was developed from the reaction of allenols having ethoxycarbonyl and vinyl group with indium trihalides at room temperature in CH2Cl2.
키워드
Allenol; 2-Halo-1,3-diene; Indium trihalide; Selectivity; CROSS-COUPLING REACTIONS; DIELS-ALDER REACTIONS; ELIMINATION-REACTIONS; ALLYL ACETATES; IN-SITU; PALLADIUM; DERIVATIVES; BROMIDES; ESTERS
- 제목
- Efficient Synthetic Method of Z-Selective 2-Halo-1,3-dienes from Reactions of Allenols Possessing Ethoxycarbonyl and Vinyl Group with Indium Trihalide
- 저자
- Eom, Dahan; Kim, Sung Hong; Lee, Phil Ho
- 발행일
- 2010-03-20
- 유형
- Article
- 권
- 31
- 호
- 3
- 페이지
- 645 ~ 649