상세 보기
초록
We report an efficient Pd-catalyzed C(sp(2))-H activation/C-O bond formation for the synthesis of ethoxy dibenzooxaphosphorin oxides from 2-(aryl) arylphosphonic acid monoethyl esters under aerobic conditions.
키워드
C-H activation; catalysis; cyclization; palladium; phosphorus heterocyclic compound; C-H OLEFINATION; ARYL HYDROGEN PHOSPHATES; BOND FORMATION SYNTHESIS; AMINO-ACID LIGANDS; UNACTIVATED C(SP(3))-H; OXIDATIVE CYCLIZATION; AMINATION REACTION; ORTHO-ALKENYLATION; ORTHO-ARYLATION; DIRECTING GROUP
- 제목
- Synthesis of ethoxy dibenzooxaphosphorin oxides through palladium-catalyzed C(sp<SUP>2</SUP>)-H activation/C-O formation
- 저자
- Shin, Seohyun; Kang, Dongjin; Jeon, Woo Hyung; Lee, Phil Ho
- 발행일
- 2014-05-23
- 유형
- Article
- 권
- 10
- 페이지
- 1220 ~ 1227