Stepwise π-extension of meso-alkylidenyl porphyrins through sequential 1,3-dipolar cycloaddition and redox reactions

Park, Dowoo; Jeong, Seung Doo; Ishida, Masatoshi; Lee, Chang-Hee

doi:10.1039/c4cc04283b

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Stepwise π-extension of meso-alkylidenyl porphyrins through sequential 1,3-dipolar cycloaddition and redox reactions

Park, Dowoo;
Jeong, Seung Doo;
Ishida, Masatoshi;
Lee, Chang-Hee

Citations

WEB OF SCIENCE

11

Citations

SCOPUS

13

초록

Several regioselectively pi-extended, pyrrole fused porphyrinoids have been synthesized by the 1,3-dipolar cycloaddition of meso-alkylidene-(benzi)porphyrins. Pd(II) complexes gave oxidation resistant, bis-pyrrole fused adducts. The repeated 1,3-dipolar cycloaddition followed by oxidation-reduction of pentaphyrin analogs afforded pi-extended porphyrin analogs.

키워드

FUSED CHLORINS; FAMILY

제목: Stepwise π-extension of meso-alkylidenyl porphyrins through sequential 1,3-dipolar cycloaddition and redox reactions

저자: Park, Dowoo; Jeong, Seung Doo; Ishida, Masatoshi; Lee, Chang-Hee

DOI: 10.1039/c4cc04283b

발행일: 2014-08-25

유형: Article

저널명: Chemical Communications

권: 50

호: 66

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