Highly efficient iridium-catalyzed oxidation of organosilanes to silanols

Lee, Y; Seomoon, D; Kim, S; Han, H; Chang, S; Lee, PH

doi:10.1021/jo035647r

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Highly efficient iridium-catalyzed oxidation of organosilanes to silanols

Lee, Y;
Seomoon, D;
Kim, S;
Han, H;
Chang, S;
외 1명

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WEB OF SCIENCE

106

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SCOPUS

111

초록

Hydrolytic oxidation of organosilanes to the corresponding silanols can be performed highly efficiently with a catalyst system of [IrCl(C8H12)](2) under essentially neutral and mild conditions, and various types of silanols are produced in good to excellent yields.

키워드

ASYMMETRIC SILICON; RHODIUM COMPLEX; ALKENYLSILANOLS; STEREOCHEMISTRY; PALLADIUM; 2-(2-HYDROXYETHYL)HOMOALLENYLSILANES; ALPHA,BETA-ENONES; SUBSTITUTION; CONVERSION; INSERTION

제목: Highly efficient iridium-catalyzed oxidation of organosilanes to silanols

저자: Lee, Y; Seomoon, D; Kim, S; Han, H; Chang, S; Lee, PH

DOI: 10.1021/jo035647r

발행일: 2004-03-05

유형: Article

저널명: The Journal of Organic Chemistry

권: 69

호: 5

페이지: 1741 ~ 1743