Xantphos as an efficient ligand for palladium-catalyzed cross-coupling reactions of aryl bromides and triflates with allyl acetates and indium

Seomoon, Dong; Lee, Phil Ho

doi:10.1021/jo702279t

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Xantphos as an efficient ligand for palladium-catalyzed cross-coupling reactions of aryl bromides and triflates with allyl acetates and indium

Seomoon, Dong;
Lee, Phil Ho

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WEB OF SCIENCE

33

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SCOPUS

35

초록

[GRAPHICS] Xantphos was found to be an efficient ligand for palladium-catalyzed allyl cross-coupling reactions of aryl bromides and triflates with allylindium reagents generated in situ from allyl acetates and indium. These reactions occur in high yield with good functional group tolerance.

키워드

IODIDE-MEDIATED ALLYLATION; GLYOXYLIC OXIME ETHER; IN-SITU; ORGANIC-REACTIONS; REDUCTIVE TRANSMETALATION; AQUEOUS-MEDIA; ONE-POT; REAGENTS; REGIOSELECTIVITY; DERIVATIVES

제목: Xantphos as an efficient ligand for palladium-catalyzed cross-coupling reactions of aryl bromides and triflates with allyl acetates and indium

저자: Seomoon, Dong; Lee, Phil Ho

DOI: 10.1021/jo702279t

발행일: 2008-02-01

유형: Article

저널명: The Journal of Organic Chemistry

권: 73

호: 3

페이지: 1165 ~ 1168