Effect of MoO3 surface coating on electrochemical performances of LiNi0.8Co0.1Mn0.1O2 cathode

초록

In this paper, we synthesize the MoO 3 modified LiNi 0.8 Co 0.1 Mn 0.1 O 2 cathode (denoted as M-NCM81) and compare with pristine LiNi 0.8 Co 0.1 Mn 0.1 O 2 cathode (denoted as P-NCM81). The M-NCM81 cathode delivers good cation ordering and typical spherical form. The M-NCM81 cathode shows initial discharge capacity of 203.8 mAh g-1 at 0.1 C, capacity retention of 79.8% under the 5.0 C. In addition, the M-NCM81 cathode still retain a discharge capacity of 172.2 mAh g (-1 )after 100 cycles. Such electrochemical performances are significantly improved compared to those of P-NCM81. It can be elucidated that MoO (3) coating layer acts as a HF inhibitor/scavenger. The MoO (3) modification plays an important role in inhibiting severe structural degradation, derived from a harmful side reaction with electrolyte. It effectively suppresses the increase in charge-transfer resistance, leading to superior electrochemical performances.

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