Hybrid System of Metal/Bronsted Acid Relay Catalysis for the Intramolecular Double Hydroarylation and Cationic Cyclization of Diyne Diethers and Diamines

Mo, Juntae; Eom, Dahan; Lee, Euichul; Lee, Phil Ho

doi:10.1021/ol301522y

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Hybrid System of Metal/Bronsted Acid Relay Catalysis for the Intramolecular Double Hydroarylation and Cationic Cyclization of Diyne Diethers and Diamines

Mo, Juntae;
Eom, Dahan;
Lee, Euichul;
Lee, Phil Ho

Citations

WEB OF SCIENCE

48

Citations

SCOPUS

50

초록

We have developed a hybrid system of metal/Bronsted acid relay catalysis for the intramolecular double hydroarylation and cationic cyclization of diyne diethers and diamines to give 4,4'-bi(2H-chromene), bi(2H-quinoline), and dioxafluoranthenes starting from 2,4-diyne-1,6-diethers and diamines in one reaction vessel under mild conditions.

키워드

C-H ACTIVATION; TANDEM CATALYSIS; ATOM ECONOMY; GOLD; CYCLOISOMERIZATION; ALKYNES; ARENES; METATHESIS; PLATINUM; INDOLES

제목: Hybrid System of Metal/Bronsted Acid Relay Catalysis for the Intramolecular Double Hydroarylation and Cationic Cyclization of Diyne Diethers and Diamines

저자: Mo, Juntae; Eom, Dahan; Lee, Euichul; Lee, Phil Ho

DOI: 10.1021/ol301522y

발행일: 2012-07-20

유형: Article

저널명: Organic Letters

권: 14

호: 14

페이지: 3684 ~ 3687