Synthesis and Dual-Emission Feature of Salen-Al/Triarylborane Dyads

Kwak, Sang Woo; Choi, Byung Hoon; Lee, Hye; Hwan, Hyonseok; Lee, Junseong; Kwon, Hyoshik; Chung, Yongseog; Lee, Kang Mun; Park, Myung Hwan

doi:10.1021/acs.inorgchem.7b00768

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Synthesis and Dual-Emission Feature of Salen-Al/Triarylborane Dyads

Kwak, Sang Woo;
Choi, Byung Hoon;
Lee, Hye;
Hwan, Hyonseok;
Lee, Junseong;
... Lee, Kang Mun;
외 3명

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초록

Novel salen-Al/triarylborane dyad complexes were prepared and characterized with their corresponding mononuclear compounds. The UV-vis and photoluminescence experiments for dyads exhibited photoinduced energy transfer from borane to the salen-Al moiety in an intramolecular manner. Theoretical calculation and fluoride titration results further supported these intramolecular energy-transfer features.

키워드

CATALYTIC CONJUGATE ADDITION; LIGHT-EMITTING-DIODES; PT-II COMPLEXES; ALPHA,BETA-UNSATURATED IMIDES; METAL-COMPLEXES; ALUMINUM COMPLEXES; PT(II) COMPOUNDS; BAND-GAP; BLUE; PHOSPHORESCENCE

제목: Synthesis and Dual-Emission Feature of Salen-Al/Triarylborane Dyads

저자: Kwak, Sang Woo; Choi, Byung Hoon; Lee, Hye; Hwan, Hyonseok; Lee, Junseong; Kwon, Hyoshik; Chung, Yongseog; Lee, Kang Mun; Park, Myung Hwan

DOI: 10.1021/acs.inorgchem.7b00768

발행일: 2017-06-05

유형: Article

저널명: Inorganic Chemistry

권: 56

호: 11

페이지: 6039 ~ 6043