Oxidative ortho-alkenylation of arylphosphine oxides by rhodium-catalyzed C-H bond twofold cleavage

Mo, Juntae; Lim, Sujin; Park, Sangjune; Ryu, Taekyu; Kim, Sanghyuck; Lee, Phil Ho

doi:10.1039/c3ra43764g

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Oxidative ortho-alkenylation of arylphosphine oxides by rhodium-catalyzed C-H bond twofold cleavage

Mo, Juntae;
Lim, Sujin;
Park, Sangjune;
Ryu, Taekyu;
Kim, Sanghyuck;
외 1명

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41

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43

초록

An efficient Rh-catalyed oxidative ortho-alkenylation is reported from the reaction of arylphosphine oxides with activated and non-activated alkenes as well. The developed method is characterized by high selectivity, a wide substrate scope, and an excellent functional group tolerance.

키워드

ARYL HYDROGEN PHOSPHATES; COUPLING REACTIONS; ORTHO-ARYLATION; DIRECTING GROUP; ACTIVATION; OLEFINATION; FUNCTIONALIZATION; ESTERS; CYCLIZATION; ALKENES

제목: Oxidative ortho-alkenylation of arylphosphine oxides by rhodium-catalyzed C-H bond twofold cleavage

저자: Mo, Juntae; Lim, Sujin; Park, Sangjune; Ryu, Taekyu; Kim, Sanghyuck; Lee, Phil Ho

DOI: 10.1039/c3ra43764g

발행일: 2013

유형: Article

저널명: RSC Advances

권: 3

호: 40

페이지: 18296 ~ 18299