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초록
An efficient phosphaannulation by Pd-catalyzed carbonylation of C-H bonds of phosphonic and phosphinic acids for the synthesis of oxaphosphorinanone oxides is reported. These compounds are novel phosphorus heterocyclic scaffolds, thus opening a new avenue to sequential C-C/C-O bond formation in one pot.
키워드
REGIOSELECTIVE CARBONYLATION; OXIDATIVE CARBONYLATION; C(SP(3))-H BONDS; BETA-LACTAMASE; ACTIVATION; ARYL; INHIBITION; ALKENYLATION; CYCLIZATION
- 제목
- Phosphaannulation by Palladium-Catalyzed Carbonylation of C-H Bonds of Phosphonic and Phosphinic Acids
- 저자
- Shin, Seohyun; Jeong, Yeonseok; Jeon, Woo Hyung; Lee, Phil Ho
- 발행일
- 2014-06-06
- 유형
- Article
- 저널명
- Organic Letters
- 권
- 16
- 호
- 11
- 페이지
- 2930 ~ 2933