상세 보기
초록
Vinyl allenols obtained from reaction of aldehydes with vinyl propargyl bromide and indium underwent Diels-Alder reactions with a variety of symmetric and unsymmetric dienophiles in dichloromethane or toluene regioselectively, producing cyclohexenylmethyl alcohols possessing an exo methylene moiety in good to excellent yield.
키워드
Alcohols; Cycloaddition; Indium; Allenes; Regioselectivity; CROSS-COUPLING REACTIONS; GENERATED IN-SITU; ONE-POT; EFFICIENT SYNTHESIS; ALLYL ACETATES; PALLADIUM; INDIUM; ARYL; STEREOCHEMISTRY; CYCLOADDITION
- 제목
- An Effective Diels-Alder Reaction of Vinyl Allenols with Dienophiles
- 저자
- Choi, Subin; Hwang, Hoon; Lee, Phil Ho
- 발행일
- 2011-03
- 유형
- Article
- 권
- 2011
- 호
- 7
- 페이지
- 1351 ~ 1356