A novel one-pot synthesis of secondary alcohols from esters

Chae, Min Jung; Jeon, Ah Ram; Park, Jae Kyo; An, Duk Keun

doi:10.1016/j.tetlet.2011.02.005

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A novel one-pot synthesis of secondary alcohols from esters

Chae, Min Jung;
Jeon, Ah Ram;
Park, Jae Kyo;
An, Duk Keun

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5

초록

Alkylation or vinylation by using organometallic reagents after partial reduction of carboxylic esters with LDBBA gave secondary alcohols, also involving allyl alcohols, without any isolation of intermediates in good yield (54-78%). (c) 2011 Elsevier Ltd. All rights reserved.

키워드

T-BUTOXYALUMINUM HYDRIDE; ACID-MEDIATED REACTION; ALLYLIC ALCOHOLS; ENANTIOSELECTIVE SYNTHESIS; DIPEPTIDE ISOSTERES; AMINO-ACIDS; ALDEHYDES; ACETALS; REARRANGEMENT; DERIVATIVES

제목: A novel one-pot synthesis of secondary alcohols from esters

저자: Chae, Min Jung; Jeon, Ah Ram; Park, Jae Kyo; An, Duk Keun

DOI: 10.1016/j.tetlet.2011.02.005

발행일: 2011-04-06

유형: Article

저널명: Tetrahedron Letters

권: 52

호: 14

페이지: 1718 ~ 1720