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초록
An organoindium generated from the reaction of indium with allenylmethyl bromide is an efficient nucleophile in Pd-catalyzed cross-couplings, producing 1,3-butadienes; cross-couplings followed by [4 + 2] cycloadditions gave six-membered carbocycles in a one-pot process.
키워드
2-(1,3-BUTADIENYL)MAGNESIUM CHLORIDE; LEWIS-ACID; CONFIGURATION; METATHESIS; 1,3-DIENES; CHEMISTRY; ALDEHYDES; ROUTE
- 제목
- Palladium-catalyzed cross-couplings of 1,3-butadien-2-yl species with organoindiums generated from allenylmethyl bromide and indium
- 저자
- Kim, Sundae; Seomoon, Dong; Lee, Phil Ho
- DOI
- 10.1039/b823037d
- 발행일
- 2009
- 유형
- Article
- 호
- 14
- 페이지
- 1873 ~ 1875