Facile mechanochemical synthesis of non-stoichiometric silica-carbon composite for enhanced lithium storage properties

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초록

A large number of new electrode materials and novel structural designs are emerging for lithium-ion batteries, yet scalable synthesis and raw material costs still hinder the practical application of such materials. Here, we designed and fabricated a low-cost SiOx/C composite by a facile and scalable mechanofusion route with a ball-milling method. We selected aerosil and graphite precursor-needle coke, which are two widely used materials in industry, as a silicon source and carbon source, respectively. This SiOx/C composite shows a high reversible capacity (ca. 550 mAh g(-1)) at the 180th cycle and good rate performance. Our scalable synthesis route of electrode materials can stimulate the progress of other energy storage technologies for practical applications. (C) 2019 Elsevier B.V. All rights reserved.

키워드

Lithium ion batteries; Mechanofusion; Aerosil; Needle coke; Si-based anodes; ANODE MATERIAL; ELECTROCHEMICAL PROPERTIES; SIOX/C COMPOSITE; HIGH-CAPACITY; LI; NANOPARTICLES; PERFORMANCE; DEPOSITION; BEHAVIORS; MECHANISM
제목
Facile mechanochemical synthesis of non-stoichiometric silica-carbon composite for enhanced lithium storage properties
저자
Zhang, Bo; Wang, Hongwei; Liu, Chang; Li, Dejun; Kim, Hyun-Kyung; Harris, Chris; Lao, Cheng-yen; Abdelkader, Amr; Xi, Kai
DOI
10.1016/j.jallcom.2019.06.101
발행일
2019-09-15
유형
Article
저널명
Journal of Alloys and Compounds
권
801
페이지
658 ~ 665