Synthesis of new Pb-based layered cuprates in (Pb,S)(Sr,La)CuOz compounds

초록

The effect of sulfate substitution on the formation of (Pb,S)-1201 type phase was investigated. Polycrystalline samples with nominal compositions of (Pb0.5B0.5-xSx)(Sr2-yLay)CuOz, (x = 0 – 0.5, y = 0.7 – 1.0) and (Pb0.5S0.5)(Sr2-yLay)CuOz (y = 0.5 – 1.0) were prepared by using a solid-state reaction method. The samples were characterized by powder X-ray diffraction (XRD) and resistivity measurements. XRD data revealed that almost-single (Pb,S)-1201 phase samples could be obtained for x = 0.5 and y = 0.9-1.0, judging from the similar results of the XRD patterns between the (Pb,S)-1201 and (Pb,B)-1201 phases. Each of the samples has a crystal structure with tetragonal symmetry. The sample with x = 0.5 and y = 0.9 is found to show an onset of resistivity dropping at over 23 K and zero resistivity at 12 K.

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