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Iridium-Catalyzed Cyclative Indenylation and Dienylation through Sequential B(4)-C Bond Formation, Cyclization, and Elimination from o-Carboranes and Propargyl Alcohols
- Baek, Yonghyeon;
- Cheong, Kiun;
- Ko, Gi Hoon;
- Han, Gi Uk;
- Han, Sang Hoon;
- ... Lee, Kooyeon;
- 외 2명
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78초록
Described herein is the first iridium-catalyzed cyclative indenylation through sequential B(4)-C and intramolecular C-C bond formation from o-carboranes and propargyl alcohols, leading to the formation of B(4)-indenylated o-carboranes with excellent regioselectivity via direct B-H activation. Moreover, the iridium-catalyzed regioselective 1,3-dienylation has been accessed through sequential B-H activation, dehydration, and decarboxylation, producing B(4)-dienylated o-carboranes.
키워드
CAGE B-H; BORON CLUSTERS; DRUG DISCOVERY; ACTIVATION; CHEMISTRY; FUNCTIONALIZATION; ALLENYLATION; AROMATICITY
- 제목
- Iridium-Catalyzed Cyclative Indenylation and Dienylation through Sequential B(4)-C Bond Formation, Cyclization, and Elimination from o-Carboranes and Propargyl Alcohols
- 저자
- Baek, Yonghyeon; Cheong, Kiun; Ko, Gi Hoon; Han, Gi Uk; Han, Sang Hoon; Kim, Dongwook; Lee, Kooyeon; Lee, Phil Ho
- 발행일
- 2020-06-03
- 유형
- Article
- 권
- 142
- 호
- 22
- 페이지
- 9890 ~ 9895
- 언어
- ENG
- 출판사
- AMER CHEMICAL SOC
- 발행국가
- 미국
- 분량
- 6 페이지
- ISSN
- E 1520-5126
P 0002-7863