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초록
A new stereoselective synthesis of trisubstituted alkenes is developed. Hydrophosphoryloxylation of haloalkynes provides Z-alkenyl halophosphates, which undergo Pd-catalyzed consecutive cross-coupling reactions to afford regio- and stereodefined trisubstituted alkenes.
키워드
CATALYZED ADDITION; CONVENIENT PRECURSORS; ORGANOBORONIC ACIDS; EFFICIENT SYNTHESIS; ENOL PHOSPHATES; ALKYNES; REAGENTS; CONVERSION; AMINATION; COUPLINGS
- 제목
- A regio- and stereoselective synthesis of trisubstituted alkenes via gold(I)-catalyzed hydrophosphoryloxylation of haloalkynes
- 저자
- Chary, Bathoju Chandra; Kim, Sunggak; Shin, Doosup; Lee, Phil Ho
- 발행일
- 2011
- 유형
- Article
- 권
- 47
- 호
- 27
- 페이지
- 7851 ~ 7853