Close-packed SiO2/poly(methyl methacrylate) binary nanoparticles-coated polyethylene separators for lithium-ion batteries

초록

In an endeavour to improve not only the thermal shrinkage but also the electrochemical performance of separators in lithium-ion batteries, a novel composite separator is developed, i.e., a close-packed SiO2/poly(methyl methacrylate) (PMMA) binary nanoparticles-coated polyethylene (PE) separator. The introduction of SiO2 nanoparticles to the coating layer effectively suppresses thermal shrinkage of the composite separator. In contrast to a SiO2/PMMA coating layer having a film-shaped PM MA binder, the SiO2/PMMA binary nanoparticle coating layer employs PMMA particles as a binder. As a consequence, a highly porous structure. i.e., well-connected interstitial voids, is formed between the binary SiO2 and PMMA nanoparticles. The unique porous morphology allows favourable liquid electrolyte wettability and facile ionic conduction, which play a crucial role in improving cell performance such as the discharge capacity and the C-rate capability of the composite separator. (c) 2010 Elsevier B.V. All rights reserved.

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