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Bronsted Acid Catalyzed Intramolecular Hydroarylation for the Synthesis of Cycloalkenyl Selenides and Tellurides
- Eom, Dahan;
- Park, Sangjune;
- Park, Youngchul;
- Lee, Kooyeon;
- Hong, Gilbert;
- 외 1명
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33초록
Trifluoromethanesulfonic acid catalyzed intramolecular hydroarylation of alkynyl selenides and tellurides is developed for the preparation of cycloalkenyl selenide and telluride derivatives through a selective 6- and 7-endo mode. The cycloalkenyl selenides and tellurides can be easily converted into a wide range of other valuable functionalities, including cyclic olefins, allylic alcohols, enynes, 1,3-dienes, and ,-unsaturated aldehydes.
키워드
Synthetic methods; Hydroarylation; BrOnsted acids; Alkenes; Selenium; Tellurium; CROSS-COUPLING REACTIONS; UNACTIVATED VINYL HALIDES; STEREOSELECTIVE-SYNTHESIS; STEREOSPECIFIC SYNTHESIS; TERMINAL ALKYNES; BOND FORMATION; NUCLEOPHILIC SUBSTITUTIONS; REGIOSELECTIVE SYNTHESIS; ORGANIC TELLURIDES; CARBONYL-COMPOUNDS
- 제목
- Bronsted Acid Catalyzed Intramolecular Hydroarylation for the Synthesis of Cycloalkenyl Selenides and Tellurides
- 저자
- Eom, Dahan; Park, Sangjune; Park, Youngchul; Lee, Kooyeon; Hong, Gilbert; Lee, Phil Ho
- 발행일
- 2013-05
- 유형
- Review
- 권
- 2013
- 호
- 13
- 페이지
- 2672 ~ 2682
- 언어
- ENG
- 출판사
- WILEY-V C H VERLAG GMBH
- 발행국가
- 독일
- 분량
- 11 페이지
- ISSN
- E 1099-0690
P 1434-193X