Photodissociation dynamics of formic acid at 193 nm

초록

The photodissociation dynamics of formic acid at 193 nm has been investigated by measuring laser induced fluorescence spectra of OH fragments. From the spectra, fraction of the available energy distributed among the products has been found to be, f<inf>r</inf>(OH) = 0.05, f<inf>t</inf> = 0.82, f<inf>int</inf>(CHO) = 0.13, with a negligible fraction of OH being in excited vibrational states. Together with the measured vector correlations, the detailed dynamics of the dissociation process has been discussed.

키워드