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Catalyst-free and solvent-free hydroboration of alkynes
- Jaladi, Ashok Kumar;
- Choi, Hyeon Seong;
- An, Duk Keun
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WEB OF SCIENCE
27Citations
SCOPUS
28초록
The hydroboration of alkynes with pinacolborane (HBpin) under catalyst- and solvent-free conditions was demonstrated. Various alkynes were smoothly converted into alkenyl boronate esters in good to excellent yields at 110 degrees C. The gram-scale hydroboration of alkynes provided the corresponding boronates, which were further utilized for various chemical transformations and coupling reactions.
키워드
CROSS-COUPLING REACTIONS; SELECTIVE HYDROBORATION; TRANS-HYDROBORATION; ALKENES; RHODIUM; MILD
- 제목
- Catalyst-free and solvent-free hydroboration of alkynes
- 저자
- Jaladi, Ashok Kumar; Choi, Hyeon Seong; An, Duk Keun
- 발행일
- 2020-08-28
- 유형
- Article
- 권
- 44
- 호
- 32
- 페이지
- 13626 ~ 13632
- 언어
- ENG
- 출판사
- ROYAL SOC CHEMISTRY
- 발행국가
- 영국
- 분량
- 7 페이지
- ISSN
- E 1369-9261
P 1144-0546