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Bismuth-catalyzed synthesis of anthracenes via cycloisomerization of o-alkynyldiarylmethane
- Park, Jungmin;
- Choi, Hyuck;
- Lee, Deug-Chan;
- Lee, Kooyeon
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3초록
In this study, anthracenes were efficiently synthesized from o-alkynyldiarylmethane using a novel method that exploits the synergistic effect between Bi(OTf)(3) as the catalyst, and trifluoroacetic acid(TFA). Through this reaction, we achieved the rapid and efficient synthesis of anthracenes bearing various functional groups under mild conditions. (C) 2015 Published by Elsevier Ltd.
키워드
Anthracene; Hydroarylation; Bismuth; Bronsted acid; Catalysis; CYCLIZATION; HYDROARYLATION; ROUTE
- 제목
- Bismuth-catalyzed synthesis of anthracenes via cycloisomerization of o-alkynyldiarylmethane
- 저자
- Park, Jungmin; Choi, Hyuck; Lee, Deug-Chan; Lee, Kooyeon
- 발행일
- 2015-12-16
- 유형
- Article
- 권
- 56
- 호
- 50
- 페이지
- 7005 ~ 7007