Bismuth-catalyzed synthesis of anthracenes via cycloisomerization of o-alkynyldiarylmethane

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초록

In this study, anthracenes were efficiently synthesized from o-alkynyldiarylmethane using a novel method that exploits the synergistic effect between Bi(OTf)(3) as the catalyst, and trifluoroacetic acid(TFA). Through this reaction, we achieved the rapid and efficient synthesis of anthracenes bearing various functional groups under mild conditions. (C) 2015 Published by Elsevier Ltd.

키워드

AnthraceneHydroarylationBismuthBronsted acidCatalysisCYCLIZATIONHYDROARYLATIONROUTE
제목
Bismuth-catalyzed synthesis of anthracenes via cycloisomerization of o-alkynyldiarylmethane
저자
Park, JungminChoi, HyuckLee, Deug-ChanLee, Kooyeon
DOI
10.1016/j.tetlet.2015.10.111
발행일
2015-12-16
유형
Article
저널명
Tetrahedron Letters
56
50
페이지
7005 ~ 7007