Ionization energy of acetone by vacuum ultraviolet mass-analyzed threshold ionization spectrometry

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초록

Mass-analyzed threshold ionization (MATI) time-of-flight mass spectrometer using coherent vacuum ultraviolet (VUV) laser generated by four-wave difference frequency mixing (FWDFM) in Kr has been constructed and utilized to obtain the accurate ionization energy of acetone. From the MATI onsets measured from various applied pulsed fields, the ionization energy to the ionic ground state of acetone has been determined to be 9.7074 +/- 0.0019 eV.

키워드

Vacuum ultraviolet laser; Mass-analyzed threshold ionization; Four-wave difference frequency mixing; Kr cell; Pulsed field ionization; N-RADICAL CATION; RYDBERG SPECTRA; SPECTROSCOPY
제목
Ionization energy of acetone by vacuum ultraviolet mass-analyzed threshold ionization spectrometry
저자
Kim, Jae Han; Kang, Do Won; Hong, Yong Jun; Hwang, Hyonseok; Kim, Hong Lae; Kwon, Chan Ho
DOI
10.1007/s10751-012-0648-x
발행일
2013-04
유형
Proceedings Paper
저널명
Hyperfine Interactions
권
216
호
1-3
페이지
85 ~ 88