Rhodium-Catalyzed Oxidative Cyclization of Arylphosphonic Acid Monoethyl Esters with Alkenes: Efficient Synthesis of Benzoxaphosphole 1-Oxides

Ryu, Taekyu; Kim, Jaeeun; Park, Youngchul; Kim, Sanghyuck; Lee, Phil Ho

doi:10.1021/ol401775t

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Rhodium-Catalyzed Oxidative Cyclization of Arylphosphonic Acid Monoethyl Esters with Alkenes: Efficient Synthesis of Benzoxaphosphole 1-Oxides

Ryu, Taekyu;
Kim, Jaeeun;
Park, Youngchul;
Kim, Sanghyuck;
Lee, Phil Ho

Citations

WEB OF SCIENCE

73

Citations

SCOPUS

74

초록

Rhodium-catalyzed tandem oxidative alkenylation and an intramolecular oxy-Michael reaction were developed using arylphosphonic acid monoethyl esters and alkenes under aerobic conditions, which produced benzoxaphosphole 1-oxides in good to excellent yields.

키워드

C-H ACTIVATION; ARYL HYDROGEN PHOSPHATES; N BOND FORMATION; DIRECTING GROUP; ROOM-TEMPERATURE; ORTHO-ARYLATION; BENZOIC-ACIDS; PALLADIUM; PHOSPHORUS; OLEFINATION

제목: Rhodium-Catalyzed Oxidative Cyclization of Arylphosphonic Acid Monoethyl Esters with Alkenes: Efficient Synthesis of Benzoxaphosphole 1-Oxides

저자: Ryu, Taekyu; Kim, Jaeeun; Park, Youngchul; Kim, Sanghyuck; Lee, Phil Ho

DOI: 10.1021/ol401775t

발행일: 2013-08-02

유형: Article

저널명: Organic Letters

권: 15

호: 15

페이지: 3986 ~ 3989