Structural, Transport, and Magnetic Properties of (Ru0.9Nb0.1)Sr2(Gd0.67R 0.67Ce0.66)Cu2Oz (R = Nd, Gd, and Tb)

초록

Samples with nominal compositions of (Ru0.9Nb0.1)Sr-2(Gd0.67R0.67Ce0.66)Cu2O (z) (R = Nd, Gd, Tb) were prepared, and the influence of doped rare-earth element on the structural, magnetic and superconducting properties of these samples has been investigated. Resistivity and room-temperature thermoelectric power measurements showed that the superconductivity is mainly affected by the change in the hole concentration induced by doping of the rare-earth element. All of these samples exhibited weak ferromagnetic behavior at temperatures below approximately 90 K with the branching of zero-field-cooled (ZFC) and field-cooled (FC) magnetization. In the ZFC magnetization measurements, diamagnetic transition was observed at temperatures below approximately 15 K for the R=Gd and Nd samples. Magnetization measurements also revealed that the partial substitution of Tb for Gd results in a significant enhancement of weak-ferromagnetic component of the FC magnetization, as well as an increase in the magnetic ordering temperature up to 20 K. A quite opposite behavior was observed in the FC magnetization for the case of the R=Nd sample. The experimental results are discussed in conjunction with the local structural changes in the Ru sublattice, which are induced by doping of the rare-earth element, based on the results of Rietveld refinement of the X-ray diffraction data.

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