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Heterogeneous zirconia-supported ruthenium catalyst for highly selective hydrogenation of 5-hydroxymethyl-2-furaldehyde to 2,5-bis(hydroxymethyl)furans in various n-alcohol solvents
- Han, Jusung;
- Kim, Yo-Han;
- Jang, Hyung-Seok;
- Hwang, Sung-Yeon;
- Jegal, Jonggeon;
- ... Kim, Jung Won;
- 외 1명
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53초록
5-Hydroxymethyl-2-furaldehyde (HMF) was hydrogenated to 2,5-bis(hydroxymethyl) furan (BHMF) (>99% yield) in various n-alcohol solvents using a Ru(OH)(x)/ZrO2 catalyst. The TON and TOF for the hydrogenation were calculated to be 912 and 304 h(-1), respectively.
키워드
BIOMASS CONVERSION; METAL-CATALYSTS; CHEMICALS; DIESEL; FUELS; ETHERIFICATION; CHEMISTRY; LIQUIDS; FURAN
- 제목
- Heterogeneous zirconia-supported ruthenium catalyst for highly selective hydrogenation of 5-hydroxymethyl-2-furaldehyde to 2,5-bis(hydroxymethyl)furans in various n-alcohol solvents
- 저자
- Han, Jusung; Kim, Yo-Han; Jang, Hyung-Seok; Hwang, Sung-Yeon; Jegal, Jonggeon; Kim, Jung Won; Lee, Yoon-Sik
- 발행일
- 2016
- 유형
- Article
- 저널명
- RSC Advances
- 권
- 6
- 호
- 96
- 페이지
- 93394 ~ 93397
- 언어
- ENG
- 출판사
- ROYAL SOC CHEMISTRY
- 발행국가
- 영국
- 분량
- 4 페이지
- ISSN
- E 2046-2069