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Synthesis and reactivity of [(η<SUP>6</SUP>-[32](1,3)cyclophane)Mn(CO)3][BF<su b>4]
- Kang, YJ;
- Lee, T;
- Baik, C;
- Lee, SW;
- Kang, SO;
- 외 2명
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4초록
The manganese cyclophane complex, [(eta(6)-[3(2)](1,3)cyclophane)Mn(CO)(3)][BF4] 2, was prepared by the reaction of [[3(2)](1,3) cyclophane] 1 with Mn(CO)(5)FBF3. Reaction of 2 with NaBH3CN yielded the cyclohexadienyl manganese complex [(eta(5)-6H-[3(2)](1,3)cyclophane)Mn(CO)(3)] 3. Interestingly, treatment of 3 with Mn(CO)(5)FBF3 gave the bis-manganese complex (eta(6), eta(5)-6H-[3(2)](1,3)cyclophane)[Mn(CO)(3)](2)[BF4] 4. When NaBH3CN was treated with 4, [(eta(5), eta(5)-6H,6'H-[3(2)](1,3)cyclophane)Mn(CO)(3)] 5 was isolated as yellow crystals. The structure of compounds 2 and 3 were determined by single-crystal X-ray crystallography. (C) 2004 Elsevier B.V. All rights reserved.
키워드
cyclophane; manganese compound; nucleophilic addition; NUCLEOPHILIC-ADDITION; CYCLOHEXENYLMANGANESE TRICARBONYL; ELECTROPHILIC REACTIVITY; SANDWICH COMPLEXES; CAGE COMPOUNDS; MANGANESE; HYDRIDE; 2-ELECTRON; SKELETON; ARENE
- 제목
- Synthesis and reactivity of [(η<SUP>6</SUP>-[32](1,3)cyclophane)Mn(CO)3][BF<su b>4]
- 저자
- Kang, YJ; Lee, T; Baik, C; Lee, SW; Kang, SO; Shinmyozu, T; Ko, JJ
- 발행일
- 2004-05-01
- 유형
- Article
- 권
- 689
- 호
- 9
- 페이지
- 1586 ~ 1592