Effective Partial Alkynylation of Carboxylic Acid Derivatives to Alkynyl Ketones

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10

초록

The reaction of carboxylic acid derivatives such as esters, acid chlorides and acid anhydrides with alkynyl lithiums in the presence of lithium morpholinide and BF3 center dot OEt2 gave alkynyl ketones in good yield (73-96%).

키워드

Partial alkynylationYnoneEsterAcid chlorideAcid anhydrideALPHA,BETA-ACETYLENIC KETONESEFFICIENT SYNTHESISACETYLENIC KETONESYNONESCYCLOISOMERIZATIONQUINOLINESREDUCTIONALCOHOLSPYRROLESESTERS
제목
Effective Partial Alkynylation of Carboxylic Acid Derivatives to Alkynyl Ketones
저자
Yim, Sang JunKim, Min HyeokAn, Duk Keun
DOI
10.5012/bkcs.2010.31.02.286
발행일
2010-02-20
유형
Article
저널명
Bulletin of the Korean Chemical Society
31
2
페이지
286 ~ 290