상세 보기
Polymer-supported IBX amide for mild and efficient oxidation reactions
- Jang, Hyung-Seok;
- Kim, Yo-Han;
- Kim, Young-O;
- Lee, Sang-Myung;
- Kim, Jung Won;
- 외 2명
Citations
WEB OF SCIENCE
9Citations
SCOPUS
11초록
A facile simple preparation of polymer-supported IBX amide (IBX amide resin) from chloromethyl polystyrene resin was demonstrated. The IBX amide resins were prepared with high loading levels (similar to 1.40 mmol g(-1)). These reagents were found to be mild and efficient oxidants through oxidation of a range of alcohols, sulfides and phosphites to the corresponding carbonyl, sulfoxide and phosphate compounds without over-oxidation at room temperature. Consumed IBX amide resins were reused up to five times without significant loss of oxidative activity after repetitive regeneration. (C) 2013 The Korean Society of Industrial and Engineering Chemistry. Published by Elsevier B.V. All rights reserved.
키워드
Polymer-supported oxidant; IBX amide resin; Alcohol; Sulfide; Phosphite; Oxidation; O-IODOXYBENZOIC ACID; HYPERVALENT IODINE REAGENTS; 2-IODOXYBENZOIC ACID; SELECTIVE OXIDATION; ALCOHOLS; REACTIVITY; CATALYSTS; ESTERS; CONVERSION; CHEMISTRY
- 제목
- Polymer-supported IBX amide for mild and efficient oxidation reactions
- 저자
- Jang, Hyung-Seok; Kim, Yo-Han; Kim, Young-O; Lee, Sang-Myung; Kim, Jung Won; Chung, Woo-Jae; Lee, Yoon-Sik
- 발행일
- 2014-01-25
- 유형
- Article
- 권
- 20
- 호
- 1
- 페이지
- 29 ~ 36
- 언어
- ENG
- 출판사
- ELSEVIER SCIENCE INC
- 발행국가
- 미국
- 분량
- 8 페이지
- ISSN
- E 1876-794X
P 1226-086X