Heteroleptic tris-cyclometalated iridium(III) complexes supported by an o-carboranyl-pyridine ligand

  • Bae, Hye Jin
  • Kim, Hyungjun
  • Lee, Kang Mun
  • Kim, Taewon
  • Eo, Maengsun
  • 외 3명
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초록

Heteroleptic tris-cyclometalated Ir(III) complexes supported by the o-carboranyl-pyridine (CBpy) as a novel (CN)-N-boolean AND chelating ligand were synthesized and characterized. While the CBpy ligand contributes to the electronic stabilization of complexes, their photophysical properties are dominated by 2-arylpyridine ligands.

키워드

POLYHEDRAL BORANESRHODIUM COMPLEXESHIGHLY EFFICIENTDERIVATIVESPHOSPHORESCENCEEMISSIONPOLYMERIZATIONSUBSTITUTIONAROMATICITYREACTIVITY
제목
Heteroleptic tris-cyclometalated iridium(III) complexes supported by an o-carboranyl-pyridine ligand
저자
Bae, Hye JinKim, HyungjunLee, Kang MunKim, TaewonEo, MaengsunLee, Yoon SupDo, YoungkyuLee, Min Hyung
DOI
10.1039/c3dt51019k
발행일
2013
유형
Article
저널명
Dalton Transactions
42
24
페이지
8549 ~ 8552