A robust bis-rhodium(i) complex of π-extended planar, anti-aromatic hexaphyrin[1.0.1.0.1.0]

Samala, Srinivas; Dutta, Ranjan; He, Qing; Park, Yeonju; Chandra, Brijesh; Lynch, Vincent M.; Jung, Young Mee; Sessler, Jonathan L.; Lee, Chang-Hee

doi:10.1039/c9cc09221h

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A robust bis-rhodium(i) complex of π-extended planar, anti-aromatic hexaphyrin[1.0.1.0.1.0]

Samala, Srinivas;
Dutta, Ranjan;
He, Qing;
Park, Yeonju;
Chandra, Brijesh;
... Jung, Young Mee;
외 3명

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초록

beta,beta '-Phenylene bridged hexaphyrin[1.0.1.0.1.0] (naphthorosarin), an expanded porphyrin possessing C-3v-symmetry, has been shown to possess unique electronic features. We now report a bimetallic Rh(i)-complex of naphthorosarin retaining 24 pi-antiaromatic characteristics. The two Rh(i) cations reside on opposite sides of the macrocyclic pi-system and are separated at a distance consistent with a possible Rh(i)-Rh(i) metallic bond interaction.

키워드

CARBON-HYDROGEN-BONDS; RHODIUM(III) PORPHYRIN; ACTIVATION; CYCLIZATION; ALKYLATION; REACTIVITY; RUTHENIUM

제목: A robust bis-rhodium(i) complex of π-extended planar, anti-aromatic hexaphyrin[1.0.1.0.1.0]

저자: Samala, Srinivas; Dutta, Ranjan; He, Qing; Park, Yeonju; Chandra, Brijesh; Lynch, Vincent M.; Jung, Young Mee; Sessler, Jonathan L.; Lee, Chang-Hee

DOI: 10.1039/c9cc09221h

발행일: 2020-01-16

유형: Article

저널명: Chemical Communications

권: 56

호: 5

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