Highly Selective Catalytic Hydrogenation and Etherification of 5-Hydroxymethyl-2-furaldehyde to 2,5-Bis(alkoxymethyl)furans for Potential Biodiesel Production

  • Han, Jusung; 
  • Kim, Yo-Han; 
  • Jung, Byeong Yeon; 
  • Hwang, Seung Hyun; 
  • Jegal, Jonggon; 
  • ... Kim, Jung Won; 
  • 외 1명
Citations

WEB OF SCIENCE

25
Citations

SCOPUS

24

초록

5-Hydroxymethyl-2-furaldehyde (HMF) was hydrogenated to 2,5-bis(hydroxymethyl) furan (BHMF) in various n-alcohol solvents with more than 99% yield using Ru(OH) x/ZrO2 catalyst. The BHMF in the same solvents was subsequently etherified to give 2,5-bis(alkoxymethyl) furans (BAMFs, four examples) as potential biodiesels with moderate to good yields using Amberlyst-15.

키워드

hydrogenation; biomass; ruthenium; biofuels; etherification; BIOMASS; FUELS; CONVERSION; DIESEL; CHEMICALS; ALCOHOLS
제목
Highly Selective Catalytic Hydrogenation and Etherification of 5-Hydroxymethyl-2-furaldehyde to 2,5-Bis(alkoxymethyl)furans for Potential Biodiesel Production
저자
Han, Jusung; Kim, Yo-Han; Jung, Byeong Yeon; Hwang, Seung Hyun; Jegal, Jonggon; Kim, Jung Won; Lee, Yoon-Sik
DOI
10.1055/s-0036-1589076
발행일
2017-10
유형
Article
저널명
Synlett
권
28
호
17
페이지
2299 ~ 2302