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Highly Selective Catalytic Hydrogenation and Etherification of 5-Hydroxymethyl-2-furaldehyde to 2,5-Bis(alkoxymethyl)furans for Potential Biodiesel Production
- Han, Jusung;
- Kim, Yo-Han;
- Jung, Byeong Yeon;
- Hwang, Seung Hyun;
- Jegal, Jonggon;
- ... Kim, Jung Won;
- 외 1명
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24초록
5-Hydroxymethyl-2-furaldehyde (HMF) was hydrogenated to 2,5-bis(hydroxymethyl) furan (BHMF) in various n-alcohol solvents with more than 99% yield using Ru(OH) x/ZrO2 catalyst. The BHMF in the same solvents was subsequently etherified to give 2,5-bis(alkoxymethyl) furans (BAMFs, four examples) as potential biodiesels with moderate to good yields using Amberlyst-15.
키워드
hydrogenation; biomass; ruthenium; biofuels; etherification; BIOMASS; FUELS; CONVERSION; DIESEL; CHEMICALS; ALCOHOLS
- 제목
- Highly Selective Catalytic Hydrogenation and Etherification of 5-Hydroxymethyl-2-furaldehyde to 2,5-Bis(alkoxymethyl)furans for Potential Biodiesel Production
- 저자
- Han, Jusung; Kim, Yo-Han; Jung, Byeong Yeon; Hwang, Seung Hyun; Jegal, Jonggon; Kim, Jung Won; Lee, Yoon-Sik
- 발행일
- 2017-10
- 유형
- Article
- 저널명
- Synlett
- 권
- 28
- 호
- 17
- 페이지
- 2299 ~ 2302