Synthesis of 2-Aryl-2H-benzotrizoles from Azobenzenes and N-Sulfonyl Azides through Sequential Rhodium-Catalyzed Amidation and Oxidation in One Pot

Ryu, Taekyu; Min, Jiae; Choi, Wonseok; Jeon, Woo Hyung; Lee, Phil Ho

doi:10.1021/ol501250t

상세 보기

Synthesis of 2-Aryl-2H-benzotrizoles from Azobenzenes and N-Sulfonyl Azides through Sequential Rhodium-Catalyzed Amidation and Oxidation in One Pot

Ryu, Taekyu;
Min, Jiae;
Choi, Wonseok;
Jeon, Woo Hyung;
Lee, Phil Ho

Citations

WEB OF SCIENCE

101

Citations

SCOPUS

106

초록

An efficient synthetic method of 2-aryl-2H-benzotriazoles from nonprefunctionalized azobenzenes and N-sulfonyl azides via sequential Rh-catalyzed amidation (C-N bond formation) and oxidation (N-N bond formation) with PhI(OAc)(2) in one pot is reported.

키워드

BENZYNE CLICK CHEMISTRY; C-H ACTIVATION; REDUCTIVE CYCLIZATION; BOND FORMATION; ARYLATION; AMINATION; ROUTE; FUNCTIONALIZATION; BENZOTRIAZOLES; ALKENYLATION

제목: Synthesis of 2-Aryl-2H-benzotrizoles from Azobenzenes and N-Sulfonyl Azides through Sequential Rhodium-Catalyzed Amidation and Oxidation in One Pot

저자: Ryu, Taekyu; Min, Jiae; Choi, Wonseok; Jeon, Woo Hyung; Lee, Phil Ho

DOI: 10.1021/ol501250t

발행일: 2014-06-06

유형: Article

저널명: Organic Letters

권: 16

호: 11

페이지: 2810 ~ 2813