상세 보기
초록
This work deals with the chemical characterization of glycine aqueous solution in CO<inf>2</inf> absorption. Three alkali elements were impregnated into the glycine in order to facilitate the formation of amino functionalities. The analysis by IR revealed the transformation of ammonium ions to the amino group. In addition, the NMR analysis showed that the substitution of metal cations to the chemical shift of hydrogen and carbon atoms in glycine; in order of lithium glycinate, sodium glycinate and potassium glycinate depending on the electro negativity. Meanwhile, the CO<inf>2</inf> absorption at room temperature was the highest in primary amine solution, but at the increasing temperature sodium glycinate could capture more CO<inf>2</inf> than that of the pure amine solution.
키워드
- 제목
- Characterization of glycine metal salts for CO2 absorption
- 저자
- Lim, Yun-hui; Park, Young-koo; Jo, Youngmin J.
- 발행일
- 2012
- 유형
- Article
- 저널명
- 공업화학
- 권
- 23
- 호
- 3
- 페이지
- 284 ~ 288