Zirconia-Supported Ruthenium Catalyst for Efficient Aerobic Oxidation of Alcohols to Aldehydes

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초록

We have developed the supported ruthenium catalyst (Ru(OH)x/ZrO2) that shows highly efficient catalytic performance for the oxidation of activated, nonactivated, and heterocyclic alcohols with only 1 atm of molecular oxygen as a green oxidant. The ruthenium active site gave excellent aerobic alcohol oxidation reaction (turnover number (TON) = 63 000). The catalyst was easily recovered after the reaction and could be reused without a significant loss of its catalytic performance.

키워드

SELECTIVE OXIDATIONHETEROGENEOUS CATALYSTMETALHYDROXYAPATITENANOPARTICLESCHEMISTRYSURFACEOXYGENGREENACID
제목
Zirconia-Supported Ruthenium Catalyst for Efficient Aerobic Oxidation of Alcohols to Aldehydes
저자
Kim, Yo-HanHwang, Seung-KyuKim, Jung WonLee, Yoon-Sik
DOI
10.1021/ie5009794
발행일
2014-08-06
유형
Article
저널명
Industrial & Engineering Chemistry Research
53
31
페이지
12548 ~ 12552