RegioselectiveBismuth-CatalyzedSynthesis of Pyranocoumarins and Furocoumarins from4-Hydroxycoumarinsand Propargyl Alcohols

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15
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14

초록

An efficient method for the bismuth-catalyzed regioselective synthesis of pyranocoumarins and furocoumarins has been developed from the reaction of 4-hydroxycoumarins with propargyl alcohols. The reaction proceeds through sequential propargylation and intramolecular cyclization reactions catalyzed by bismuth(III) triflate.

키워드

Bismuth; Catalysis; Pyranocoumarin; Furocoumarin; Regioselectivity; COUMARIN DERIVATIVES; NEO-TANSHINLACTONE; BISMUTH(III) COMPOUNDS; CYCLIZATION; CHEMISTRY; AGENTS; 4-HYDROXYCOUMARIN; PHENOLS; ANALOGS; CASCADE
제목
RegioselectiveBismuth-CatalyzedSynthesis of Pyranocoumarins and Furocoumarins from4-Hydroxycoumarinsand Propargyl Alcohols
저자
Kim, Jaehyun; Lee, Kooyeon; Lee, Phil Ho
DOI
10.1002/bkcs.12058
발행일
2020-07
유형
Article
저널명
Bulletin of the Korean Chemical Society
권
41
호
7
페이지
709 ~ 718