Synthesis of 6-, 7-and 8-membered cyclosiloxanes having multifunctional groups

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초록

Cyclosiloxanes having intramolecular donor atoms, a Si-Si bond, and vinyl groups were synthesized as useful precursors for ring-opening polymerization.1,1,3,3-Tetrakis(dimethylaminomethylphenyl)-5,5-dimethylcyclotrisiloxane was also synthesized and characterized by single crystal X-ray structural analysis, which shows strong coordination from N to Si in the solid state. (C) 2011 Elsevier B.V. All rights reserved.k

키워드

Organosilicon compoundCyclic siloxaneIntramolecular donor atomVinylsiloxaneSi-Si bondELECTROCHEMICAL OXIDATIONCYCLIC POLYSILANESDISILOXANE-1,3-DIOLSISOMERIZATIONBEHAVIOR
제목
Synthesis of 6-, 7-and 8-membered cyclosiloxanes having multifunctional groups
저자
Cho, Hyeon MoLee, Ji-EunLee, Myong EuyLee, Kang Mun
DOI
10.1016/j.jorganchem.2011.04.025
발행일
2011-07-15
유형
Article
저널명
Journal of Organometallic Chemistry
696
14
페이지
2754 ~ 2757