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초록
alpha,beta-Unsaturated aldehydes such as acrolein and crotonaldehyde were reacted with diols in the presence of conc. sulfuric acid to give products of which concomitant addition to C-C double bond and acetalization took place. Boron trifluoride etherate and titanium tetrachloride gave only acetalization products.
키워드
alpha,beta-unsaturated aldehydes; acetalization; addition; DIELS-ALDER REACTIONS; CYCLOADDITION REACTIONS; NITRILE OXIDES; ACETALS; CATALYST; 1,3-DIOXOLANES; ETHERS
- 제목
- Concomitant addition and acetalization of α,β-unsaturated aldehydes with diols
- 저자
- Jeon, KO; Yu, JS; Lee, CK
- 발행일
- 2004-11-20
- 유형
- Article
- 권
- 25
- 호
- 11
- 페이지
- 1653 ~ 1656