Advanced TiO2-SiO2-Biochar Thin-Film Nanocomposite Membranes for High-Performance Removal of Dyes and Heavy Metals from Wastewater

초록

Next-generation wastewater treatment and recycling rely on membrane-based processes, but they face a trade-off among permeability, selectivity, and fouling resistance. In the present study, thin-film nanocomposite (TFN) membranes were fabricated by incorporating a ternary TiO2-SiO2-biochar nanofiller into a polysulfone (PSf) support using nonsolvent-induced phase separation, after which m-phenylenediamine and trimesoyl chloride were used via interfacial polymerization to produce a selective polyamide layer. The membrane compositions were M1 (22 wt.% PSf), M2 (22 wt.% PSf/0.5 wt.% TiO2/0.5 wt.% SiO2/0.5 wt.% biochar), and M3 (polyamide-coated M2). FTIR, XRD, SEM, contact-angle, porosity, and mechanical analyses supported successful membrane formation and changes in morphology, wettability, and structural strength after nanofiller incorporation and TFC coating. The addition of a nanofiller increased the hydrophilicity of the membranes by decreasing the water contact angle from 98.6 +/- 0.8 degrees for pristine PSf to 35.6 +/- 1.5 degrees for the nanocomposite membrane. Consequently, the pure-water permeability increased from 21 to 37 L m(-2) h(-1) bar(-1). After polyamide layer formation, the optimized TFN membrane maintained a contact angle of 55.4 +/- 3.8 degrees and achieved a high Congo red rejection of 98% with permeate flux of 7-9 L m(-2) h(-1) bar(-1). The membrane also showed good antifouling performance, with flux recovery ratios exceeding 90%. For heavy-metal-containing solutions, the optimized membrane showed apparent removal efficiencies of 78-98% for multivalent heavy metals (Pb2+, Hg2+, Cd2+, Mn2+, Zn2+, Cu2+, Ni2+, Fe3+, As3+, and Cr6+). Static adsorption tests showed the order M2 > M3 > M1, confirming that exposed TiO2-SiO2-biochar sites contribute to pollutant uptake, while the superior filtration performance of M3 is attributed to the combined effect of the polyamide selective layer and adsorption-assisted interactions. Overall, the TiO2-SiO2-biochar-based TFN membrane provides a promising platform for dye removal and preliminary heavy-metal attenuation from contaminated water.

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