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Synthesis of Xanthones via Copper(II)-Catalyzed Dehydrogenative Cyclization and Successive Aromatization in a One-Step Sequence
- Jang, Yoon Hu;
- Yang, Yo-Sep;
- Son, Seung Hwan;
- Yoo, Hyung-Seok;
- Shin, Jeong-Won;
- 외 4명
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5초록
In this study, an unprecedented approach to the xanthone scaffold from cyclohexyl(2-hydroxyphenyl)methanone via dehydrogenative cyclization and a successive aromatization cascade is reported. This methodology affords a novel route to the privileged structure with a wide substrate scope (a total of 29 compounds, <= 96% yield) in a highly atom-economic manner.
키워드
PHENOLS; OXYGEN
- 제목
- Synthesis of Xanthones via Copper(II)-Catalyzed Dehydrogenative Cyclization and Successive Aromatization in a One-Step Sequence
- 저자
- Jang, Yoon Hu; Yang, Yo-Sep; Son, Seung Hwan; Yoo, Hyung-Seok; Shin, Jeong-Won; Won, Hyuck-Jae; Kim, Soo Lim; Lim, Changjin; Kim, Nam-Jung
- 발행일
- 2022-12-23
- 유형
- Article
- 저널명
- Organic Letters
- 권
- 24
- 호
- 50
- 페이지
- 9216 ~ 9221
- 언어
- ENG
- 출판사
- AMER CHEMICAL SOC
- 발행국가
- 미국
- 분량
- 6 페이지
- ISSN
- E 1523-7052
P 1523-7060