Salt (LiF) Regulated Fluorescence Switching

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초록

A supramolecular host-guest complex stimulated by lithium cation and fluoride anion, functioning as reliable fluorescence "Off-On-Off" switching system has been developed. Nonfluorescent, receptor-bound fluorophore is exclusively displaced by second guest, fluoride anion to release fluorophore that becomes highly fluorescent in guest concentration dependent way. Again, this process is completely reversed upon exposure to Li+. The entire process is an excellent model for fluorescence-based logic system.

키워드

Luminescence; Fluorescence switching; Fluorescence indicator; Calix[4]pyrrole Coumarin; Lithium fluoride; INDICATOR DISPLACEMENT ASSAY; ANION-BINDING; MOLECULAR MOTORS; ON-OFF; METAL; COMPLEXATION; RECOGNITION; SITES
제목
Salt (LiF) Regulated Fluorescence Switching
저자
Sokkalingam, Punidha; Yoo, Jaeduk; Hwang, Hyonseok; Lee, Phil Ho; Jung, Young Mee; Lee, Chang-Hee
DOI
10.1002/ejoc.201100359
발행일
2011-06
유형
Article
저널명
European Journal of Organic Chemistry
권
2011
호
16
페이지
2911 ~ 2915