Crystal structure of [1,13-bis(8-quinolyl)-1,4,7,10,13-pentaoxatridecanylprotonato]hexafluoro phosphate monohydrate

초록

The structure of the title compound, [C<inf>26</inf>H<inf>29</inf>N<inf>2</inf>O<inf>5</inf>]·PF <inf>6</inf>·H<inf>2</inf>O (= [LH]·PF<inf>6</inf>·H<inf>2</inf>O), was confirmed by low-temperature single- crystal analysis. The crystal system belongs to triclinic with a space group of P1. The crystal structure reveals that the three-dimensional skeleton of [LH]+ adopts an approximate S-shape, and the intermolecular hydrogen bond between the quinoline nitrogen atoms of the adjacent molecules leads to form a helical 1-D polymer expanded along the b-axis. 2006 © The Japan Society for Analytical Chemistry.