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New crystalline framework formed from a podal ligand with S2O2 donor and CuI:: non-interpenetrating square-grid with cubane-like CU4I4 cluster nodes
- Kim, TH;
- Lee, KY;
- Shin, YW;
- Moon, ST;
- Park, KM;
- ... Kang, YJ;
- 외 3명
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Self-assembly of CuI and 1,12-diphenyl-5,8-dioxa-2,11-dithiadodecane (L), a podal ligand with S2O2 donor set, afforded a unique square-grid type coordination polymer [Cu4I4L2](n) (1). X-ray analysis of 1 shows that cubane-like Cu4I4 clusters are located at the nodes of the square-grid and connected to four ligands by Cu-S bonds forming a layer structure. The layers are stacked with an ABAB sequence. Photoluminescence behavior of 1 was also investigated. (C) 2004 Elsevier B.V. All rights reserved.
키워드
S2O2; podal ligand; self-assembly; Cu(I) coordination polymer; square grid; luminescence thermochromism; COORDINATION POLYMERS; COMPLEXES; IONOPHORES; NETWORKS; AG(I)
- 제목
- New crystalline framework formed from a podal ligand with S2O2 donor and CuI:: non-interpenetrating square-grid with cubane-like CU4I4 cluster nodes
- 저자
- Kim, TH; Lee, KY; Shin, YW; Moon, ST; Park, KM; Kim, JS; Kang, YJ; Lee, SS; Kim, J
- 발행일
- 2005-01
- 유형
- Article
- 권
- 8
- 호
- 1
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- 27 ~ 30