Hydrophobic coatings prepared using various dipodal silane-functionalized polymer precursors

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초록

This study introduces synthetic methodology to develop hydrophobic surfaces. Hydrophobic surfaces are fabricated via cross-linking of inorganic-organic hybrids, prepared from dipodal alkoxysilane-functionalized urethane precursors (AFUS). The inorganic-organic (I-O) hybrids are synthesized by co-hydrolysis and co-condensation of various precursors. The hybrid solutions are then used to fabricate hydrophobic coatings through spin coating method. The coatings exhibited water contact angle greater than 90 degrees. The properties of the hydrophobic coatings are analysed and characterized using scanning electron microscopy (SEM) and contact angle measurement (CA). The precursors are characterized by Fourier transform infrared spectroscopy (FT-IR), thermogravimetric-differential thermal analysis (TG-DTA) and gel permeation chromatography (GPC). These environment-friendly inorganic-organic hybrid coatings have shown great potential in replacing the toxic fluorinated alkylsilane based coatings.

키워드

Hydrophobic coating; Cross-linking; Inorganic-organic hybrid; Dipodal alkoxysilane-functionalized urethane precursor; SUPERHYDROPHOBIC SURFACES; FABRICATION; ICE; CONDENSATION; AGENTS; FILMS
제목
Hydrophobic coatings prepared using various dipodal silane-functionalized polymer precursors
저자
Nambafu, Gabriel Sikukuu; Kim, Nahae; Kim, Juyoung
DOI
10.1016/j.apsadv.2021.100207
발행일
2022-02
유형
Article
저널명
APPLIED SURFACE SCIENCE ADVANCES
권
7