Palladium-catalyzed ortho-alkenylation of aryl hydrogen phosphates using a new mono-phosphoric acid directing group

Chan, Li Yan; Kim, Sunggak; Ryu, Taekyu; Lee, Phil Ho

doi:10.1039/c3cc41107a

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Palladium-catalyzed ortho-alkenylation of aryl hydrogen phosphates using a new mono-phosphoric acid directing group

Chan, Li Yan;
Kim, Sunggak;
Ryu, Taekyu;
Lee, Phil Ho

Citations

WEB OF SCIENCE

89

초록

A highly efficient Pd-catalyzed ortho-alkenylation is reported using a mono-phosphoric acid-directing group for the first time. This phosphoric acid-directing group is successfully utilized for the synthesis of various alkenylated products and offers a new approach to transition-metal-catalyzed C-H activation.

키워드

C-H ACTIVATION; ORTHO-LITHIATION; HECK REACTION; ROOM-TEMPERATURE; ORTHO-ARYLATION; ARENES; BONDS; FUNCTIONALIZATION; OLEFINATION; PHENOLS

제목: Palladium-catalyzed ortho-alkenylation of aryl hydrogen phosphates using a new mono-phosphoric acid directing group

저자: Chan, Li Yan; Kim, Sunggak; Ryu, Taekyu; Lee, Phil Ho

DOI: 10.1039/c3cc41107a

발행일: 2013

유형: Article

저널명: Chemical Communications

권: 49

호: 41

페이지: 4682 ~ 4684