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Asymmetric total synthesis of (+)-brefeldin a from (S)-lactate by triple chirality transfer process and nitrile oxide cycloaddition
- Kim, DJ;
- Lee, JK;
- Shim, PJ;
- Lim, JI;
- Jo, H;
- 외 1명
Citations
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75초록
A novel synthesis of (+)-brefeldin A (1) has been accomplished on the basis of triple chirality transfer methodology, intramolecular ester enolate alkylation, and both intra- and intermolecular nitrile oxide cycloaddition strategies.
키워드
ENOLATE CLAISEN REARRANGEMENT; NATURAL BREFELDIN-A; ENANTIOSELECTIVE SYNTHESIS; FORMAL SYNTHESIS; STEREOCONTROLLED SYNTHESIS; FACILE SYNTHESIS; CELL-SURFACE; CYCLIZATION; DERIVATIVES; APOPTOSIS
- 제목
- Asymmetric total synthesis of (+)-brefeldin a from (S)-lactate by triple chirality transfer process and nitrile oxide cycloaddition
- 저자
- Kim, DJ; Lee, JK; Shim, PJ; Lim, JI; Jo, H; Kim, SH
- 발행일
- 2002-02-08
- 유형
- Article
- 권
- 67
- 호
- 3
- 페이지
- 764 ~ 771
- 언어
- ENG
- 출판사
- AMER CHEMICAL SOC
- 발행국가
- 미국
- 분량
- 8 페이지
- ISSN
- E 1520-6904
P 0022-3263